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Rust on porcelain is usually the result of a dripping faucet and high iron content in the water. One household remedy is scrubbing the stain with a mixture of lemon juice and salt. If scrubbing doesn't do it, soaking might. Saturate a rag with the mixture and lay it on the blemish for a few hours. Then scrub it again. If there's still a stain, ask your local hardware dealer or home center about commercially available rust and iron removers.
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